It is a member of benzyl alcohols and a cnitro compound. Photocatalytic oxidation of 4 methoxybenzyl alcohol to panisaldehyde was performed in water organicfree solutions by using a fixed bed continuous photoreactor containing pyrex beads on which a. Continued stirring should leach out the alcohol and acetic acid causing the amide product to precipitate. Use of the information, documents and data from the echa website is subject to the terms and conditions of this legal notice, and subject to other binding limitations provided for under applicable law, the information, documents and data made available on the echa website may be reproduced, distributed andor used, totally or in part, for noncommercial purposes provided that echa is. Buy 3chloro4hydroxy5 methoxybenzyl alcohol cas 20624924, a product for proteomics research, from santa cruz. A simple method for the selective deprotection of p. Cetyl alcohol material safety data sheet cas no 36653824. Using phasetransfer catalyst flashcards from nathalie b. The substance identity section is calculated from substance identification information from all echa databases. Anisyl alcohol 4methoxybenzyl alcohol is an organic compound with the chemical formula ch3oc6h4ch2oh. Nov 21, 2009 a p methoxybenzyl pmb protectiondeprotection approach toward the synthesis of 5phenoxy4chloronarylalkyl thiophene2sulfonamides alfred l. Reproductive toxicity no data available 4methoxybenzyl alcohol specific target organ toxicity single exposure.
The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. About reference price about reference price reference price is published by molbase platform, which was calculated with quotation and purchasing data by scientific algorithm. This msds list has been prepared using information from sources considered technically reliable. For breathing difficulties, oxygen may be necessary. Articles of 3methoxybenzyl alcohol are included as well.
Application 4hydroxybenzyl alcohol can be used as a precursor for the synthesis of. Material safety data sheet 4 methoxybenzyl chloride sc252172 hazard alert code key. It undergoes catalytic photooxidation by flavinzinc iicyclen complex to yield the corresponding benzaldehyde. Always refer to the safety data sheet sds for detailed information on storage. Pdf selective photocatalytic oxidation of 4methoxybenzyl. Seqens international sas is supplier for 3 methoxybenzyl alcohol.
No data available 4methoxybenzyl alcohol carcinogenicity iarc. It is a violation of federal law to use these products in. It has a role as an insect repellent, a human urinary metabolite, a plant metabolite and a bacterial metabolite. May be harmful if swallowed, inhaled, or absorbed through the skin. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication.
It is a colorless liquid that is used as a fragrance and flavorant. Material safety data sheet 4hydroxy3methoxybenzyl alcohol, 99. The following products are pesticide products registered by the u. It is used to study the photo catalytic oxidation of 4 methoxybenzyl alcohol to panisaldehyde. There are two dimethoxybenzyl dmb or dmpm groups 2,4dimethoxy and 3,4dimethoxy, both of. Madhu chakrapani rao with a couple of likeminded people began the operation of the company in a small facility totalling 2000 sq ft. Extreme high moderate low section 1 chemical product and company identification product name 4 methoxybenzyl chloride statement of hazardous nature considered a hazardous substance according to osha 29 cfr 1910. Tadimety aromatics pvt ltd was founded in the year 1996. If inhaled if breathed in, move person into fresh air. Regulatory process names 1 iupac names 2 other identifiers 1. Section 1 chemical product and company identification.
Electrochemical deprotection of p methoxybenzyl pmb ethers was performed in an undivided electrochemical flow reactor in meoh solution, leading to the unmasked alcohol and pmethoxybenzaldehyde dimethyl acetal as a byproduct. Also is used as a reagent for various chemical organic reactions such as in the synthesis of quinolines. Their fine chemical facility in lahr, germany, has decades of international experience in serving. It occurs naturally but is produced by reduction of anisaldehyde. Articles of 3ethoxy4hydroxybenzyl alcohol are included as well. If released to water, benzyl alcohol is expected to undergo microbial degradation under aerobic and anaerobic conditions. Thermal hazard evaluation of 4methoxybenzyl chloride pmbcl. No component of this product present at levels greater than or equal to 0. Pmethoxybenzaldehyde is a member of the class of benzaldehydes consisting of benzaldehyde itself carrying a methoxy substituent at position 4. The information in this msds was obtained from current and reliable sources. The electrochemical method removes the need for chemical oxidants, and added electrolyte bf 4 net 4 can be recovered and reused. Keep in a tightly closed container, stored in a cooled, dry, ventilated area. Use water spray, alcohol resistant foam, dry chemical or carbon dioxide.
Synonym 4 methoxybenzyl alcohol anis alcohol panisyl alcohol anise alcohol. Replacement of paramethoxybenzyl chloride leads to a safer and shorter route. In the atmosphere, benzyl alcohol is expected to exist almost entirely in the vapor phase. This product has been replaced by 270245aldrich 4 methoxybenzyl chloride contains potassium carbonate as stabilizer, 98% protecting group reagent for alcohols. Electrochemical deprotection of paramethoxybenzyl ethers. Show this safety data sheet to the doctor in attendance. This product has been replaced by 270245aldrich 4methoxybenzyl chloride contains potassium carbonate as stabilizer, 98%. Sigmaaldrich is a leading life science and high technology company dedicated to providing highquality, safe and certified flavor ingredients with transparent and easily accessible documentation to customers around the globe. A simple method for the selective deprotection of p methoxybenzyl ethers by ceriumiii chloride heptahydrate and sodium iodide anna cappa, enrico marcantoni, and elisabetta torregiani dipartimento di scienze chimiche, via s.
The msds listed above reflects the chemicals found in the inventory of the chemistry and biology departments of usc upstate. Relevant identified uses of the substance or mixture and uses advised against. The estimated halflife for the vapor phase reaction of benzyl alcohol with photochemically produced hydroxyl radicals is 2. Safety data sheet according to 29cfr19101200 and ghs rev.
Oct 22, 2005 thermal hazard evaluation of 4methoxybenzyl chloride pmbcl. Cool the mixture in an ice bath, collect the solid and rinse with a small amount of. Sigmaaldrich material safety data sheet product name 4. We are seller of acetylendicarboxylic acid mono potassium salt. The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the molecular and structural formulas. Oxidizing methoxybenzyl alcohol to methoxybenzaldehyde. Anisyl alcohol 4methoxybenzyl alcohol is an organic compound with the chemical formula ch 3 oc 6 h 4 ch 2 oh. Hbaincorporated copolyoxalate hpox nanoparticles as potential drug delivery system. Study 23 oxidizing methoxybenzyl alcohol to methoxybenzaldehyde. Anisyl alcohol 4 methoxybenzyl alcohol is an organic compound with the chemical formula ch 3 oc 6 h 4 ch 2 oh. It can also be deprotected under mildly oxidizing conditions using ddq dichlorodicyanobenzoquinone or strongly acidic conditions.
The oldest independent swiss chemical company, chemie uetikon has a longstanding commitment to the chemical industry. A diverse range of products, all meeting our stringent commitment to quality. The perfect blend of products and services that bring your creativity to life. Changes in the unbound pyridine chemical shifts with added 4 methoxybenzyl alcohol, benzyl alcohol, and 4chlorobenzyl alcohol. Synonym 4 methoxybenzyl alcohol anis alcohol panisyl alcohol anise alcohol formula c8 h10 o2 molecular weight 8. This substance has been found in the following regulatory activities directly, or inheriting the regulatory context of a parent substance. Synonym 4hydroxy3 methoxybenzyl alcohol formula c8 h10 o3.
It undergoes catalytic photooxidation by flavinzinciicyclen complex to yield the corresponding benzaldehyde. Synonym 4hydroxy3methoxybenzyl alcohol formula c8 h10 o3 molecular weight 154. Structure, properties, spectra, suppliers and links for. Firstaid measures if breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the. Mechanistic characterization of aerobic alcohol oxidation. The substance identity section is calculated from substance identification information from all echa. Sigmaaldrich material safety data sheet date printed.
654 426 216 1238 1250 979 203 1086 1069 1082 1449 620 783 1085 968 308 629 1534 353 1427 846 700 1167 1373 420 1403 175 150 1419 13 384 316 395